Urgent! Please Help

May I ask if you have an CNAME or A record for your sub-domain study.piacademy.co.uk?
Also, is the DNS record for that sub-domain :orange: or :grey: cloud?

Moreover, what SSL option have you got selected at Cloudflare dashboard? (Flexible SSL, Full SSL …)

Have you had an SSL certificate already installed at your host/origin server?
If yes, does the SSL certificate cover your sub-domain hostname?

Here are the steps regarding the DNS_PROBE_FINISHED_NXDOMAIN:

Moreover, as tested, I got 521 error.
Have you tried looking for a fix here?
Kindly, follow the steps in the article and the post from below to solve your issue:
https://support.cloudflare.com/hc/en-us/articles/115003011431-Troubleshooting-Cloudflare-5XX-errors#521error

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